Laboratory Evaluation
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Ever-Charge
Advanced 'Eco' Battery Re-charger
by Ben Duncan*
*BDR Labs UK, July 2006
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Appearance-wise, The 'Ever Charge' charger is superficially like any regular NiCad (rechargeable battery) charger. Except that it has switchable settings for the newer & vastly better Nickel Hydride (strictly, Nickel Metal Hydride, NiMH) cells and layer batteries. And also, central to this report, a third setting - to 'recharge' Alkaline cells and batteries. These are colloquially known by various trade names. The use of the word 'charge' in the context of Alkaline cells & batteries, may cause justifiable concern for some readers. Instead, one may say 'rejuvenate' or 'reconstitute'. See 'Terminology' (later) for a further discussion. Our Tests - The following text is essentially factually identical to the report issued to the distributor & maker, with changes being limited mainly to enhancements in the English (language) style, added descriptions and background information, and refined emphases. Test methodology The nominal (published) capacities were used to designate (very) approximately commensurate integer loads for the 3 cell sizes, of 1, 2 and 4 times the current, for AAA, AA and D respectively. The cells & batteries, obtained 'fresh' from a retail outlet, had the usual unknown capacity loss ('pre-discharge') due to storage. They were then discharged using the above-designated loads. The duration, to a given endpoint, established a 'spot' capacity, taken to be 100%. Due to the unknown degree of pre-discharge*1, circa 5% max, a recharge to above 100% of this capacity is not unfeasible. *1As any primary battery loses some of its charge or chemical potential, as soon as it is manufactured. Conditions Ambient temperatures happened to range between 23 & 29 C (span of 6 C) during the tests and recharges; But by no more than 3 C during any one test. Equipment
It was not necessary to use the most modern equipment to make the tests. The
following equipment, while dating from 1964 to 1984, is highly regarded, all
British made & designed, and has been fully restored, regularly maintained
and calibration checked. 1 - Alkaline Cells Three of the four de facto standard sizes were tested - D, AA & AAA. What was found was interesting. Initially cells were discharged to 1.10 volts -
on a load approximately commensurate to capacity. This is the end-point indicated
on a typical cell condition test meter, where the needle is lying between the
yellow & red sections. This was initially felt to meet the manual's instruction
"...alkaline batteries should be completely drained before recharging with ..." 2 - Alkaline Battery (PP3 size)
Also known as a 'Layer Cell'. This type requires time and care to discharge fully. Moving on, full, deep (near 100%) discharge, to below 0.1 volt, was then carried out, by leaving the already discharged and partially recharged alkaline PP3 battery connected to the discharging load, for over 3 days (above 72 hours). After recharge, the charge capacity was improved - on a heavy load to some 35%, which while not as good as the cells managed, is still 'plenty useful'. Imagine a clock, where the battery has already lasted 4 years; the load will be light, so the effective recharge will probably amount to nearer 50%, so another two years could be had. At the same time, this is rather inferior to the recharging performance of the single cells (A thro' D). But it needs emphasising that this is believed to be down to one cell not charging fully, or even entering or remaining, in reverse or shorted modes. However, putting matters into context, such problems of charging (or re-conditioning) series cells, are typical with, and in common to, all battery systems that employ cells in series. And the problems of 'serised' cells gets worse with higher currents (relative to cell size). Also when there are only a few cells in series, a disproportionate part of the voltage can be lost. And things are bad when there are not adequately conceived control mechanisms, that more specialist operations can afford. For example, if PP3 packs were made of separable cells, a bad one could be changed. Saving needless landfill. NiCad PP3s and electric tool NiCad packs are just two examples of batteries made short lived by this situation. The problem - that just one cell can by itself, disrupt the whole show - occurs with all forms of battery power, where voltages above the (generally) 1.2 to 3v per single cell, are required. It is equally inevitable at the end of life, that one cell fails before the others. A Ben Duncan recommendation is that to be 'better rechargeable', the traditional layer battery really needs redesigning with diodes and related electronic content, to control cell voltage sharing. A part that would ideally be pluggable, so it could be re-used when such batteries reached end of their chemical (but not electronic) life. Reviewer's Recommendations * Changes to manual to clarify need to discharge quite adequately & fully.
* It would be preferable to see changes to the charger to provide for discharge,
and indication of deep-enough discharge. For both cells, and PP3 batteries. An
incandescent lamp is suggested, as its operation can be seen, and the deep enough
discharge will involve lamp filaments that are not visibly illuminated in
daylight. This is a good measure. "Discharge until the lamp's glow is no longer
visible in daylight." * Changes to the charger, such that PP3 battery charging is better able to be monitored. * It occurs to us that the charger (in the version we tested) may not in fact be principally designed to recharge alkaline PP3 cells, and that the charging via the PP3 'clips' is primarily optimised for NiCads, with the usual constant current method. This may need checking. (and clarifying in the manual) The following addition, or similar, to the Manual's text, is recommended: "The Ever-Charge can 'replenish' most, if not all types, of alkaline (and related manganese alkaline) cells, provided they have been preferably freshly and quite fully discharged. Intelligent control of the charge current (up to 130mA) enables alkaline cells to be safely 'recharged', initially up to nearly 100% of their first use capacity. And then up to 30 more times, with (naturally enough) gradually reducing capacity. It's helpful to realise that batteries & cells are 'chemical activity centres' somewhat like living objects, and those that are have been left fully ('deep') discharged for above a few days, or aged 'surplus' stock (maybe kept in bad conditions - you may need to ask why they are being sold as a 'bargain'), or cells of lesser quality, may not 'recharge' at all; or so deeply, nor so often, before they are incapable of giving much more usable service life. Deep discharge can be checked - the cells will not light a torch lamp visibly; or the light is so feeble it can only be seen as a dull orange'ish glow in a dark place. The Ever-Charge system does not recharge alkaline cells in the same way as NiCads or car batteries. It refurbishes or reconditions chemicals, so that the valuable content is not wasted, and can be fully utilised. Once used, it is used. But, on a keymost environmental note, even just one' recharge' halves the amount (per unit time), of alkaline battery waste, that is going into landfill. Sad to realise that most of it has, before now, been quite needless - as the Ever Charge shows that up to 90% of the chemical content of discarded alkaline batteries was not really finished. But, that is now history. Like cars that easily rusted. |
"The Ever Charge shows that up to 90% of the chemical content of discarded
alkaline batteries was not really finished. But, that is now history."
The reconditioning or 'recharging' of alkaline cells has been possible for many years, but without fairly detailed microprocessor control, it was hitherto not necessarily safe outside of the technically minded and alert operator. Some cells would get hot, and unless monitored with alarms, this might happen at any time, with sealed cells either exploding, or leaking their contents. This is the basis that battery makers may correctly warn users from using chargers. But, the Ever-Charge system identifies bad, such as short circuited, cells (as 'BAD'), and will not charge/ recondition them. Making the charging process very safe." It is additionally recommended that the manual is in any event generally rewritten, in quality international English. The product is rather unnecessarily let down by the 'Chinglish' pidgin. Test Conclusions Overall, it is confirmed that the charger does re-charge or re-condition alkaline cells, such that they are substantially able to re-perform up to their initial discharge capacity. And, this need only happen once to be extremely useful. We can also confirm that with alkaline cells, subsequent re-charges to a significant percentage of the original capacity, were also recorded - provided the discharging just beforehand was adequate. There are some minor problems with the manual and the PP3 alkaline management; otherwise, the unit is a highly workable eco-aid. And will quickly pay for itself in many businesses and households. Why Rejuvenate? The high cost of non-rechargeable batteries has been complained about since they were first used en-masse, in the 1880s, for phone exchanges and doorbells. Even at today's high prices, mains electricity remains vastly cheaper - by a factor of at least a hundred times. Rechargeable NiCad cells and batteries that would fit in the place of
regular cells and batteries have been 'around' - for the public - for some
35 years. Originally, their use was limited to 'professional' users - like
the military. They originally required careful recharging, and were quite
costly. NiCad and now NiMH rechargeable cells have since become more worthwhile,
with prices (per amount of energy stored) that are far lower in real terms than
10 or 20 years ago. Alkaline cells' benefits, added to the opportunity for reducing the gross level of "premature disposance" that they've suffered from beforehand, may paradoxically see them used more widely, while far fewer are still disposed of, per unit time. "It is said, that at this time, 15,000 million alkaline cells are disposed of annually, across the world."Terminology Recharge vs. Reconstitute The use of the word 'recharge' is at the heart of any problems felt to exist by scientific pedants, and the most likely cause of upset by those who know (just) a little about chemistry and physics. The reason is simply that any alkaline cell is a primary type. In primary cells, the chemical reactions which generate EMF, are not reversible. To do work, the cell must "eat itself", or at least gradually neutralise its active constituents. So, the sort of reversible chemical action that goes on in secondary cells (such as in NiCad and NiMH types, and car batteries), when they are charged, is not strictly what is going on when alkaline cells are 'recharged'. However, our tests clearly showed that alkaline cells and batteries (see sidebar) were able to do extra work - and stay working - as a result of using the charger. The bottom line - of using the same energy supply device more than once, if not many times, before needing to spend money on a replacement - is identical. Also, in everyday parlance, it's not unreasonable to call such a process 'recharging', considering the term is also viably used by tired humans having a quick sleep, who are also not secondary cells! To satisfy the gravitas of a technical article, and in order to emphasise that the mechanism of energy-delivering recovery is different -than in secondary, rechargeables, terms like 'rejuvenate' and 'reconstitute', may be substituted. Cells vs. Batteries Sizes AAA, A, C and D 'batteries' are strictly, cells. A basic 'power unit' of around 1.2v to 1.5v, depending on the chemistry employed. The PP3 'mini power pack' is truly a battery, but is also known as a 'layer cell' or 'stack' - as it comprises 'a battery of' 6 cells, in a special flat format, stacked in layers. Primary & Secondary Cells (and Batteries) Primary cells & batteries are everyday non-rechargeables. Mostly, they are either low cost, basic zinc-carbon types (which have been around for over 100 years), and the higher-tech (manganese-) alkaline replacements (which began use 50 years ago), or later, mainly incremental developments of these. Some 3W-borne Background Information- considered to be authoritative A well written US site, on battery history: Alkaline battery chemistry, from a foremost British science centre: Alkaline battery patents & history from the Austrian genius who invented the technology: Some Historic Background Reading A.S.Henderson, Nickel-Cadmium secondary cells, Wireless World, March 1982. Testing and review was independently performed, and Ben Duncan Research is in no way affiliated or has interest in, the Ever Charge system. In being e cologically aware however, we cannot fail to approve of the initiative taken. Other that demonstrating product review & investigative capacities, this text may be seen by the many former readers, as resting in place of a hypothetical, technical product review in the former and foremost worldwide, British-published electronics technology podium, Wireless World, more recently known as 'EW+WW'. RIP. BD - 22nd Sept 2006 |